sell it to him and be happy with 40 bones. you might get an offer for 50 soon, or you'll never hear anyting on it again. loose tires are a very random thing, not much demand untill the right person needs one.
off the top of my head a discount tire store will sell that tire for around $90 new if one did enough shopping.
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x2. "Brand new" means to me, that not only doesn't it have any miles, but it's a fairly recent tire and it's not been mounted. Yeah, the mounting doesn't mean much, but a 2 year old tire is a 2 year old tire, mileage or no.